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発行日時
2019/6/13 10:30
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Carnegie Mellon researchers develop semi-liquid lithium metal anode for use with solid electrolytes
リンクURL
https://www.greencarcongress.com/2019/06/20190613-cmu.html Carnegie Mellon researchers develop semi-liquid lithium metal anode for use with solid electrolytesへの外部リンク
記事詳細
Researchers from Carnegie Mellon University’s Mellon College of Science and College of Engineering have developed a semiliquid lithium metal-based anode (SLMA) that represents a new paradigm in battery design for solid electrolyte batteries. The interdisciplinary research team published their findings in the current issue of Joule. Solid electrolytes are considered to be key components for next-generation lithium metal-based rechargeable batteries. However, to implement a solid electrolyte with lithium metal still remains a challenge because of the insufficient contact between the solid/solid interface. To address this shortcoming, we have created a novel suspension-based liquid/solid interface by employing solid electrolytes with a semiliquid lithium metal anode (SLMA) that is flowable at room temperature. The SLMA consists of lithium microparticles evenly distributed in a dual-conductive polymer matrix. In a symmetric cell with a garnet-based solid electrolyte, the SLMA shows stable lithium stripping and plating behavior with low overpotential at the current density of 1 mA/cm2 and 1 mAh/cm2 for nearly 400 h. This work shows a significant improvement over previous work based on lithium anode with the same type of solid electrolyte. The method used in this work has great potential for building reliable alkaline metal-based rechargeable batteries.—Li et al. One proposed solution to the volatile liquid electrolytes used in current batteries is to replace them with solid ceramic electrolytes. These electrolytes are highly conductive, non-combustible and strong enough to resist dendrites. However, researchers have found that the contact between the ceramic electrolyte and a solid lithium anode is insufficient for storing and supplying the amount of power needed for most electronics. Sipei Li, a doctoral student in Carnegie Mellon’s Department of Chemistry, and Han Wang, a doctoral student in Carnegie Mellon’s Department of Materials Science and Engineering, were able to surmount this shortcoming by creating a new class of material that can be used as a semiliquid metal anode. Working with the Mellon College of Science’s Matyjaszewski, a leader in polymer chemistry and materials science, and Jay Whitacre, Trustee Professor in Energy in the College of Engineering and director of the Wilton E. Scott Institute for Energy Innovation at Carnegie Mellon, who is known for his work in developing new technologies for energy storage and generation, Li and Wang created a dual-conductive polymer/carbon composite matrix that has lithium microparticles evenly distributed throughout. The matrix remains flowable at room temperatures, which allows it to create a sufficient level of contact with the solid electrolyte. By combining the semiliquid metal anode with a garnet-based solid ceramic electrolyte, they were able to cycle the cell at 10 times higher current density than cells with a solid electrolyte and a traditional lithium foil anode. This cell also had a much longer cycle-life than traditional cells. This new processing route leads to a lithium metal-based battery anode that is flowable and has very appealing safety and performance compared to ordinary lithium metal. Implementing new material like this could lead to step change in lithium-based rechargeable batteries, and we are working hard to see how this works in a range of battery architectures.—Jay Whitacre The researchers believe that their method could have far reaching impacts. For example, it could be used to create high capacity batteries for electric vehicles and specialized batteries for use in wearable devices that require flexible batteries. They also believe that their methods could be extended beyond lithium to other rechargeable battery systems, including sodium metal batteries and potassium metal batteries and might be able to be used in grid-scale energy storage. This research was funded by the National Institutes of Health and the National Science Foundation. Resources Sipei Li, Han Wang, Julia Cuthbert, Tong Liu, Jay F. Whitacre, Krzysztof Matyjaszewski (2019) “A Semiliquid Lithium Metal Anode” Joule doi: 10.1016/j.joule.2019.05.022